Indicate the number of carbons in each of the three chains that start from the bridgehead carbons in the following bicycles.
SOLUTION:
Molecule 1.
Bicyclo[1.1.0]butane
The bridgeheads (red) are linked by two 1-carbon chains. The third chain has 0 carbons [1.1.0].
Molecule 2.
Bicyclo[1.1.1]pentane
The bridgehead carbons (red) are linked by 3 one-carbon chains. [1.1.1]
Molecule 3.
Bicyclo[2.1.0]pentane
Chains of 2,1 and 0 carbons start from the bridgehead carbons (red). [2.1.0]
Molecule 4.
Bicyclo[2.1.1]hexane
Chains of 2, 1 and 1 carbons start from the bridgehead carbons (red). [2.1.1]
The following examples describe in more detail how to identify the values that go inside the bracket.