**SUBJECT 1. ALKANES**

**Problems** : Alkanes problems

**UNIT 2. RADICAL HALOGENATION REACTIONS**

**SUBJECT 3. CYCLOALKANES **

**Problems:** Cycloalkanes problems

**SUBJECT 4. STEREOCHEMISTRY**

**Theory:** Structural isomers | Geometric isomers | Enantiomers | Diastereomers | Enantiomer nomenclature | Racemic mixture and meso form | Optical activity | Fischer projection | R/S notation in Fischer | Molecules with several centers | Stereochemistry of the reactions | Stereospecific reaction | Separation of enantiomers.

**Problems:** Stereochemistry problems

**SUBJECT 5. REACTIONS OF SUBSTITUTION AND ELIMINATION**

**S Theory _{N} 2:** Haloalkanes nomenclature | Physical properties of haloalkanes | Mechanism of the S

_{N}2 | Energy diagram of S

_{N}2 | Stereochemistry of S

_{N}2 | Ring size at S

_{N}2 speed | Outgoing group in S

_{N}2 | Nucleophile in SN2 | Substrate in S

_{N}2 | Solvent in S

_{N}2 |

**Theory S**Mechanism of the S

_{No}1:_{N}1 | SN1 energy diagram | Stereochemistry in S

_{N}1 | Outgoing group in S

_{N}1 | Nucleophile in S

_{N}1 | Substrate in SN1 | Solvent in S

_{N}1 | Competition Y

_{N}2 and Y

_{N}1.

**Elimination Theory:** Elimination Reactions E1 (Unimolecular Elimination) | E2 (Bimolecular elimination) | Elimination with prevented bases.

**Problems** : Problems Y _{N} 2 | SN1 problems | Problems Elimination

**SUBJECT 6. ALKENES**

**Problems:** Alkene problems

**SUBJECT 7. REACTIONS OF ALKENES**

**Theory:** Catalytic hydrogenation in alkenes | Addition of HX to alkenes | Markovnikov rule in alkenes | Addition of Water to Alkenes | Addition of halogens to alkenes | Other electrophilic additions to alkenes | Oxymercuriation-demercuriation of alkenes | Hydroboration in alkenes | MCPBA oxidation of alkenes | Opening of epoxides (oxacyclopropanes) | Oxidation with permanganate and osmium tetraoxide of alkenes | Ozonolysis of alkenes | Radical reactions of alkenes | Alkene polymerization.

**Problems** : Alkene reaction problems

**SUBJECT 8. ALKYNES **

**Problems:** Alkyne problems

**SUBJECT 9. ALLYLIC SYSTEMS**

**UNIT 10. DIELS-ALDER REACTION**

**SUBJECT 11. ALCOHOLS **

**Problems:** Alcohol problems

**SUBJECT 12. ETHERS**

**Theory:** Ethers nomenclature and properties | Williamson synthesis of ethers | Ethers from alcohols | Protecting groups | Ethers via SN1 | Opening of oxacyclopropanes (epoxides).

**Problems:** Ethers Problems

**SUBJECT 13. ALDEHYDES AND KETONES **

**Problems:** Carbonyl problems

**SUBJECT 14. ENOLS AND ENOLATES**

**Problems:** Enol and enolate problems

**SUBJECT 15. BENZENE**

**Issues:** Benzene Issues

**SUBJECT 16. CARBOXYLIC ACIDS**

**Problems:** Carboxylic Acid Problems

**SUBJECT 17. DERIVATIVES OF CARBOXYLIC ACIDS**

Order of reactivity | Acid-base behavior

**ALKANOYL HALIDES**

**Problems:** Acid Halide Problems

**ANHYDRIDES**

**Theory:** Anhydride Nomenclature | Anhydride Reactivity

**ESTERS**

**Problems :** Esters Problems

**AMIDES**

**Problems:** Amide Problems

**NITRILES**

**Problems:** Nitrile problems

**SUBJECT 18. DIFUNCTIONAL COMPOUNDS**

**Theory:** Acetylacetic synthesis | Malonic synthesis | Knoevenagel condensation | Michael's addition

**SUBJECT 19. AMINES**

**Problems:** Amine problems

**UNIT 20. SILICON, PHOSPHORUS AND SULFUR COMPOUNDS**