Safety Data Sheet (SDS) - Ethyl Acetate
1. Identification
Product Name: Ethyl Acetate
CAS Number: 141-78-6
Chemical Formula: C4H8O2
Synonyms: Acetic acid ethyl ester, Ethyl ethanoate
2. Hazard Identification
Classification:
Flammable Liquid (Category 2)
Eye Irritation (Category 2)
Specific Target Organ Toxicity - Single Exposure (Category 3)
Label Elements:
Signal Word: Warning
Hazard Statements:
H225: Highly flammable liquid and vapor.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
Precautionary Statements:
P210: Keep away from heat, sparks, open flames, hot surfaces. No smoking.
P264: Wash hands thoroughly after handling.
P280: Wear protective gloves/eye protection.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P403+P235: Store in a well-ventilated place. Keep cool.
3. Composition/Information on Ingredients
Chemical Name | CAS Number | Concentration (%)
Ethyl Acetate | 141-78-6 | ≥ 99%
4. First-Aid Measures
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Call a physician.
Skin Contact: Wash off immediately with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation develops.
Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes, lifting the upper and lower eyelids. Get medical attention if irritation persists.
Ingestion: Do NOT induce vomiting. Rinse mouth. Call a physician immediately.
5. Fire-Fighting Measures
Suitable Extinguishing Media: Foam, dry powder, carbon dioxide, water fog.
Unsuitable Extinguishing Media: Do not use a solid water stream, as it may spread the fire.
6. Accidental Release Measures
Personal Precautions: Wear protective equipment. Keep unprotected persons away.
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not let the product enter drains.
7. Handling and Storage
Handling: Use only in a well-ventilated area. Avoid breathing vapors. Avoid contact with eyes, skin, and clothing.
Storage: Keep away from heat, sparks, and open flame. Keep containers tightly closed in a cool, well-ventilated place.
8. Exposure Controls/Personal Protection
Engineering Controls: Use local exhaust ventilation.
Personal Protective Equipment:
Eye Protection: Safety glasses or goggles.
Hand Protection: Chemical-resistant gloves.
Respiratory Protection: If ventilation is inadequate, use respiratory protection.
9. Physical and Chemical Properties
Appearance: Clear, colorless liquid
Odor: Fruity, pleasant
Melting Point: -83.6°C
Boiling Point: 77.1°C
Flash Point: -4°C
Density: 0.902 g/cm³
10. Stability and Reactivity
Stability: Stable under normal conditions.
Materials to Avoid: Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
11. Toxicological Information
Acute Toxicity:
Oral: LD50 > 5,000 mg/kg (Rat)
Dermal: LD50 > 2,000 mg/kg (Rabbit)
Inhalation: LC50 > 5,000 ppm/4h (Rat)
Skin Irritation: Mild irritant (Rabbit)
Eye Irritation: Moderate irritant (Rabbit)
12. Ecological Information
Ecotoxicity: LC50 > 1,000 mg/L (Fish)
Environmental Fate: Ethyl acetate is biodegradable.
13. Disposal Considerations
Dispose of in accordance with local, regional, and national regulations.
14. Transport Information
UN Number: 1173
Class: 3
Packing Group: II
15. Regulatory Information
United States: TSCA Listed
Canada: DSL Listed