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SUBSTITUTION REACTIONS (SN1)
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Let the overall reaction be:

diagrama-energia-sn1

The mechanism occurs in three steps

diagrama-energia-sn1

The energy vs. reaction coordinate diagram has the following form:

diagrama-energia-sn1
The first stage has the highest activation energy and controls the rate of the overall process. The final deprotonation is very fast and its activation energy is very low.