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Details: German Fernandez; Views: 8207

CONTENT

1. INTRODUCTION

2. DIELS ALDER MECHANISM

3. DIELS ALDER STEREOCHEMISTRY

4. DIELS ALDER WITH CYCLIC DIENES 5.

INTRAMOLECULAR DIELS ALDER 6.

DIELS ALDER WITH ALKYNES

7. RETRO-DIELS-ALDER

8. PHOTOCHEMICAL CYCLOADDITIONS

9. ELECTROCYCLIC REACTIONS

Details: German Fernandez; Views: 7629

CONTENT

1. INTRODUCTION

2. RESONANCE IN ALLYLIC SYSTEMS

3. SN1 IN ALLYLIC SYSTEMS

4. KINETIC AND THERMODYNAMIC CONTROL

5. SN2 IN ALLYLIC SYSTEMS

6. SN2 PRIME

7. ELIMINATIONS 1,4

8. RADICAL REACTIONS IN ALLYLICS

9. CONJUGATED DIENES

10. ADDITION OF HX A CONJUGATED DIENES

11. ADDITION OF BROMINE TO CONJUGATED DIENES

Details: German Fernandez; Views: 9333

CONTENT

1. INTRODUCTION

2. MECHANISM

3. ENERGY DIAGRAM

4. REACTIVITY OF HALOGENS

5. STABILITY OF RADICALS

6. PRODUCT DISTRIBUTION

7. HALOGENING AGENTS

8. RESOLVED PROBLEMS

Details: German Fernandez; Views: 8463

CONTENT

1. INTRODUCTION

2. NOMENCLATURE OF ALKYNES

3. STRUCTURE AND BONDING IN ALKYNES

4. PHYSICAL PROPERTIES OF ALKYNES

5. ACID HYDROGEN IN TERMINAL ALKYNES

6. STABILITY OF ALKYNES

7. ISOMERIZATION OF ALKYNES

8. OTHER COMPOUNDS WITH CARBONS SP: ALLENES

9. ALKYNES BY DOUBLE ELIMINATION

10. ALKYNES BY ALKYLATION

11. HYDROGENATION OF ALKYNES

12. MONOELECTRON REDUCTION TO ALKENES trans

13. HYDROBORATION OF ALKYNES

14. REACTION OF ALKYNES WITH HX

15. REACTION OF ALKYNES WITH HALOGENS

16. HYDRATION OF ALKYNES

17. CATIONIC CYCLATIONS

Details: German Fernandez; Views: 13110

CONTENTS

1. INTRODUCTION
2. NOMENCLATURE OF HALOALKANES
3. PHYSICAL PROPERTIES OF HALOALKANES
4. SN2 (BIMOLECULAR NUCLEOPHILIC SUBSTITUTION)
5. SN1 (UNIMOLECULAR NUCLEOPHILIC SUBSTITUTION)
6. SN2 / SN1 COMPETITION
7. E1 (UNIMOLECULAR ELIMINATION)
8. EBI (BIMOLECULAR ELIMINATION
) 9. COMPETITION SUBSTITUTION / ELIMINATION)

Details: German Fernandez; Views: 6464

CONTENT

1. INTRODUCTION

2. NOMENCLATURE OF CYCLOALKANES

3. ANNULAR STRESS

4. CYCLOPROPANE

5. CYCLOBUTANE 6.

CYCLOPENTANE

7. CYCLOHEXANE CONFORMATIONS

8. CONFORMATIONAL EQUILIBRIUM IN CYCLOHEXANE

9. SUBSTITUATED CYCLOHEXANES

10. SOLVED PROBLEMS

Details: German Fernandez; Views: 12743

CONTENT

1. INTRODUCTION
2. STRUCTURAL ISOMERS 3. GEOMETRIC ISOMERS
4. ENANTIOMERS
5. DIASTEREOISOMERS
6. NOMENCLATURE OF ENANTIOMERS
7. RACEMIC MIXTURE AND MESO FORM
8. OPTICAL ACTIVITY
9. MOLECULES WITH SEVERAL CHIRAL CENTERS
10. FISCHER PROJECTION
11. STEREOCHEMISTRY OF THE REACTIONS
12. STEREOSELECTIVE AND STEREOSPECIFIC REACTION
14. SEPARATION OF ENANTIOMERS