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The reaction of ketones [1] with peracids [2] produces esters [3] .
The oxygen of the peracid is inserted between the carbonyl carbon and the alpha carbon of the ketone. This reaction was described by Adolf von Baeyer and Victor Villiger in 1899. Read more...
The Wittig reaction uses phosphorus ylides [2] to transform aldehydes and ketones [1] into alkenes [3] . Triphenylphosphine oxide is obtained as a by-product [4].
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Cyanohydrins [3] are formed by the reaction of aldehydes or ketones [1] with hydrocyanic acid [2] and are compounds that contain a cynane and a hydroxy group on the same carbon.
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This is a specific analytical assay for aldehydes and ketones. Carbonyls [1] react with 2,4-Dinitrophenylhydrazine [2] to form phenylhydrazones [3] which precipitate yellow.
The appearance of a precipitate is an indicator of the presence of carbonyls in the medium. Read more...
Hydrazine [2] reacts with two aldehyde molecules [1] to form azines [3].
Read more...
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- German Fernandez
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OrganicChemistry.org Newsletter
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organic reactions
Organic Synthesis (Wilbert Rivera)
Forum
Conformations of cis and trans 1- tert -butyl-4-methoxycyclohexane
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OrganicChemistry.org Newsletter
Dear [NAME], I am attaching some content from the web, hoping that it will be of interest to you.
Structural Determination
Determination of molecular formulas
Publications
Photoinduced metalation of C-Cl bonds with samarium diiodide
Opening of epoxides and aziridines promoted by hot water
organic reactions
Organic Synthesis (Wilbert Rivera)
Synthesis of General Anesthetics
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Substitution and Elimination Reactions
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Bulletin nº4 of QuímicaOrgánica.org (January 2016)
Dear [NAME], I am attaching some content from the web, hoping that it will be of interest to you.
Structural Determination
Organic Chemistry I
organic reactions
Organic Synthesis (Wilbert Rivera)
Methodologies in organic synthesis
General principles of the synthesis tree method
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Synthesis of alcohols by reaction of esters with organometallics.
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