♦ Tension $C\equiv N$: very thin band at 2250 cm-1
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IR spectrum: Nitriles
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Organic Chemistry Book
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- Benzene - Problem 16
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- The benzylic position
- Aromatic nucleophilic substitution by addition-elimination
- Protection of activated positions
- Reduction of nitro to amino and oxidation of amino to nitro
- Synthesis of 1,2-dicarbonyl compounds
- Synthesis of 1,3-dithianes
- benzoin condensation
- acyloinic condensation
- Knoevenagel condensation
- Michael's addition
- Review of Claisen condensation
- helical molecules
- Rp and Sp notation in planes of chirality
- Ra/Sa notation on chirality axes
- R/S notation in stereogenic centers
- Elements of asymmetry leading to chiral molecules
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- conformational analysis
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- Phosphines and phosphorus ylides
- Synthesis of 1,3-dithianes. UMPOLUNG reactions
- Thioacetals, hydrolysis and reduction to alkanes
- ylides of sulfur
- Sulphoxide removal WITHOUT
- The Thioethers
- thiols
- simulation of the infrared spectrum of propanamide
- Simulation of the infrared spectrum of 1-butanamine
- Simulation of the infrared spectrum of ethyl ethanoate
- Simulation of the infrared spectrum of ethanoyl chloride
- Simulation of the infrared spectrum of propanoic acid
- Simulation of the infrared spectrum of ethanenitrile
- Simulation of the infrared spectrum of diethyl ether
- Simulation of the infrared spectrum of ethanal
- Simulation of the infrared spectrum of 2-butanone
- Simulation of the infrared spectrum of 1-propanol
- Guareschi-Thorpe synthesis of pyridine
- Kröhnke synthesis of pyridine
- Pomerantz-Fritsch synthesis of isoquinolines
- Pictet Spengler synthesis of isoquinoline
- Bischer–Napieralski synthesis
- Friedlander quinoline synthesis
- Combes synthesis of quinolines
- Alkyl and vinyl quinolines and isoquinolines
- Nucleophilic substitution in quinoline and isoquinoline
- Nucleophilic addition to quinolines and isoquinolines
- Lithiation reaction in quinoline and isoquinoline
- Electrophilic substitution by N-oxides
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- Nucleophilic substitution by elimination-addition: the pyridine
- Nucleophilic substitution reactions in pyridine
- Nucleophilic addition reactions to pyridines
- pyridine lithiation
- Electrophilic substitution at position 4 of pyridine
- Synthesis of thiophene by 1,3-dipolar
- Paal–Knorr synthesis of thiophene
- Furan synthesis by 1,3-dipolar
- Feist-Benary synthesis of furan
- Paal–Knorr synthesis of furans
- Synthesis of pyrrole via 1,3-dipolar
- Hantzch synthesis of pyrrole
- Paal–Knorr synthesis of pyrrole
- furan opening
- Derivatives of pyrrole, thiophene and furan
- Cycloaddition reactions in furan
- Lithiation reaction
- Nucleophilic substitution in pyrrole, thiophene and furan
- nucleophilic addition
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- Sulfonation, formylation, Mannich and acetylation of furan
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- Indole derivatives
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- Electrophilic substitution at the indole
- indole acidity
- Examples of fused heterocycle nomenclature
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- Rules for the choice of the base component
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- General characteristics of diazines
- Cyclization of carbenes nitrenes and radicals
- Cyclization on sp carbons
- Cyclization processes by nucleophilic addition and addition-elimination at sp¹²2 carbons
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- Classification of nucleophilic attacks (Baldwin's Rules)
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- Synthesis of heterocycles by cyclization reactions
- The anomeric effect