Unimolecular deletions (E1) compete with unimolecular nucleophilic substitution (SN1), forming alkenes.

 
eliminacion-unimolecular
 
The nucleophilic behavior of water generates the substitution product (S N 1), while the basic character gives rise to the elimination product (E1).
 
The mechanism of the E1 reaction occurs with the following steps:
 
Stage 1. Ionization of the substrate
 
eliminacion-unimolecular
 
Stage 2. The water acts as a base, removing the proton from the carbon next to the positive one (beta carbon), to form the alkene.
 
eliminacion-unimolecular
 
If water acts as a nucleophile, it gives rise to products of the SN1 type. The low basicity of water means that the substitution product is in the majority.