Print
THEORY OF CYCLOALKANES
Hits: 159333

Cycloalkanes are alkanes that have the chain ends joined together, forming a cycle. They have two fewer hydrogens than the alkane from which they are derived, which is why their molecular formula is CnH2n . They are named using the prefix cyclo followed by the name of the alkane.

cycloalkanes nomenclature 01

[1] Cyclopropane

[2] Cyclobutane

[3] Cyclopentane

[4] Cyclohexane


It is common to represent molecules indicating only their skeleton. Each vertex represents a carbon bonded to two hydrogens.

cycloalkanes nomenclature 02

The IUPAC rules for naming cycloalkanes are very similar to those studied for alkanes.

Rule 1.- In cycloalkanes with a single substituent, the cycle is taken as the main chain of the molecule. Cycle numbering is unnecessary.

cycloalkanes nomenclature 03

[4] Ethylcyclobutane

[5] Isopropylcyclohexane

[5] Methylcyclopentane


If the side chain is complex, it can be taken as the main chain of the molecule and the cycle as a substituent. Cycloalkanes as substituents are named by changing the ending –ane to –yl.

cycloalkanes nomenclature 04

[7] Cyclopropyl

[8] Cyclobutyl

[9] Cyclopentyl

[10]Cyclohexyl

 

Rule 2.- If the cycloalkane has two substituents, they are named in alphabetical order. The cycle is numbered starting with the substituent that comes before it in the name.

 

cycloalkanes nomenclature 05

[11] 3-Cyclopropyl-2-methyloctane

[12] 1-Cyclopentyl-3-methylhexane


Rule 3.- If the ring has three or more substituents, they are named in alphabetical order. The numbering of the cycle is done in such a way that the lowest locants are given to the substituents.

 

cycloalkanes nomenclature 07

[14] 1-Bromo-2-ethyl-4-methylcyclopentane

[15] 2-Bromo-1-chloro-3-methylcyclopentane


In case of obtaining the same locants when numbering starting with different positions, the alphabetical order is taken into account.

cycloalkanes nomenclature 08

[16] 1-Ethyl-3-methylcyclopentane

[17] 1-Bromo-3-chlorocyclohexane